Skip to main content

Switching Mechanisms in Wurtzite-type Ferroelectrics

Mar 5, 2026

•Wurtzite-type ferroelectrics are attractive for integration with semiconductors but generally require enormous coercive fields, approaching breakdown, to reverse their polarization. The underlying switching mechanism(s) remain elusive.

•We use detailed first-principles calculations to reveal previously-unidentified polarization switching mechanisms in wurtzite-type FEs and develop design rules that can be directly translated to actionable recommendations for lowering coercive fields.

•We reveal a new switching mechanism – via the inversion of individual tetrahedra – that departs from the commonly-assumed mechanism in prior literature. We also report different non-polar intermediate structures that may provide clues to domain wall structures.

•The individual switching mechanism is associated with more complex energy landscapes with (potentially) lower overall energy barriers and is unlocked by increasing chemical complexity.

Authors

Geoff Brennecka and Prashun Gorai (Colorado School of Mines)

Additional Materials

U.S. National Science Foundation and NSF DMREF, Materials for Our Future

This material is based upon work supported by the U.S. National Science Foundation Award No. 2015237. Any opinions, findings, and conclusions or recommendations expressed in this material are those of the author(s) and do not necessarily reflect the views of the U.S. National Science Foundation. This site is maintained collaboratively by principal investigators with NSF DMREF awards, independent of the NSF.